Chen Ya-Li, Hau Chun-Kit, Wang Hao, He Hao, Wong Man-Shing, Lee Albert W M
Department of Chemistry and Centre for Advanced Luminescence Materials, Hong Kong Baptist University, Kowloon Tong, Hong Kong, China.
J Org Chem. 2006 Apr 28;71(9):3512-7. doi: 10.1021/jo060099d.
Mono- and bis-oxadisilole-fused isobenzofurans were first synthesized and isolated. A series of mono-, bis-, and tris-oxadisilole-substituted acenes were then synthesized by benzyne Diels-Alder reactions with the isobenzofurans. The photophysical, redox, and thermal properties of these new acenes were characterized.
首次合成并分离出单氧杂二硅杂环戊二烯并异苯并呋喃和双氧杂二硅杂环戊二烯并异苯并呋喃。然后通过苯炔狄尔斯-阿尔德反应，用这些异苯并呋喃合成了一系列单、双和三氧杂二硅杂环戊二烯取代的并苯。对这些新型并苯的光物理、氧化还原和热性质进行了表征。
