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快速蒸发聚合物溶液中的图案化:不良溶剂蒸发下环形结构的形成。

Patterning in rapidly evaporated polymer solutions: formation of annular structures under evaporation of the poor solvent.

作者信息

Bormashenko Edward, Pogreb Roman, Musin Albina, Stanevsky Oleg, Bormashenko Yelena, Whyman Gene, Barkay Zahava

机构信息

The Research Institute, The College of Judea and Samaria, 44837 Ariel, Israel.

出版信息

J Colloid Interface Sci. 2006 Aug 1;300(1):293-7. doi: 10.1016/j.jcis.2006.03.064. Epub 2006 Apr 3.

DOI:10.1016/j.jcis.2006.03.064
PMID:16626728
Abstract

Patterning in the intensively evaporated polymer solutions based on polystyrene and poor solvent (acetone) was investigated. SEM and AFM studies demonstrated that annular elements of the surface topography are formed in this case, in contrast to the honeycomb patterns obtained under the evaporation of the good solvent (chloroform). The authors suggest that the theory of viscous dewetting developed by de Gennes explains the phenomenon satisfactorily.

摘要

研究了基于聚苯乙烯和不良溶剂(丙酮)的强烈蒸发聚合物溶液中的图案化现象。扫描电子显微镜(SEM)和原子力显微镜(AFM)研究表明,与在良溶剂(氯仿)蒸发下获得的蜂窝状图案不同,在这种情况下会形成表面形貌的环形元素。作者认为,德热纳提出的粘性去湿理论能够令人满意地解释这一现象。

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