由双齿苯氧基酰胺配体负载的高活性钛基烯烃聚合催化剂。
Highly active titanium-based olefin polymerization catalysts supported by bidentate phenoxyamide ligands.
作者信息
Oakes Daniel C H, Gibson Vernon C, White Andrew J P, Williams David J
机构信息
Imperial College, Exhibition Road, London SW7 2AZ, UK.
出版信息
Inorg Chem. 2006 May 1;45(9):3476-7. doi: 10.1021/ic060146k.
PMID:16634572
Abstract
Phenoxyamide complexes of Ti-containing 2,6-X2C6H3 (X = Cl, Br) substituents, when activated by methyl aluminoxane, afford catalysts with very high activities for the polymerization of ethylene and with good incorporation of 1-hexene.
摘要
含2,6-X2C6H3（X = Cl，Br）取代基的钛的苯氧基酰胺配合物，在经甲基铝氧烷活化后，可提供对乙烯聚合具有非常高活性且对1-己烯具有良好插入率的催化剂。
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