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cis-Diaquabis[(E)-4-(2-hydroxybenzylideneamino)benzoato-kappa2O,O']cadmium(II): two-dimensional layers built from strong O-H...O hydrogen bonding in the coordination sphere.

作者信息

Yao Shu-Qin, Zhu Miao-Li, Lu Li-Ping, Gao Xiao-Li

机构信息

Institute of Molecular Science, Key Laboratory of Chemical Biology and Molecular Engineering of the Education Ministry, Shanxi University, Taiyuan, Shanxi 030006, People's Republic of China.

出版信息

Acta Crystallogr C. 2006 May;62(Pt 5):m183-5. doi: 10.1107/S0108270106009723. Epub 2006 Apr 13.

DOI:10.1107/S0108270106009723
PMID:16679577
Abstract

In the title compound, [Cd(C14H10NO3)2(H2O)2], which crystallizes with Z = 4 in the space group C2c, the Cd atom is located on a twofold rotation axis and coordinated by six O atoms from two water molecules and two carboxylate groups of two planar 4-(2-hydroxybenzylideneamino)benzoate ligands, with a dihedral angle of 85.6 (1) degrees between them. Strong O-H...O hydrogen bonding in the coordination sphere, together with pi-pi stacking interactions, assemble the molecules into two-dimensional layers.

摘要

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