Pawar Vijay D, Bettigeri Sampada, Weng Shiue-Shien, Kao Jun-Qi, Chen Chien-Tien
Department of Chemistry, National Taiwan Normal University, Taipei, Taiwan.
J Am Chem Soc. 2006 May 17;128(19):6308-9. doi: 10.1021/ja060639o.
An unprecedented vanadyl(V) methoxide complex 4 derived from 3,5-dibromo-N-salicylidene-l-tert-leucinate enables highly enantioselective aerobic oxidations of alpha-hydroxyphosphonates at ambient temperature with selectivity factors ranging from 3 to >99.
一种由3,5-二溴-N-水杨醛缩-1-叔亮氨酸衍生而来的前所未有的甲醇钒（V）配合物4，能够在室温下实现α-羟基膦酸酯的高度对映选择性有氧氧化，选择性因子范围为3至>99。
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