Braga Antonio L, Schneider Paulo H, Paixão Marcio W, Deobald Anna M, Peppe Clovis, Bottega Diana P
Departamento de Química, Universidade Federal de Santa Maria, Santa Maria, RS, 97105-900, Brazil.
J Org Chem. 2006 May 26;71(11):4305-7. doi: 10.1021/jo060286b.
A simple and efficient procedure for the synthesis of chiral beta-seleno-amines derivatives from a one-pot indium(I) iodide-mediated aziridine ring opening with diorganoyl diselenides has been developed. As an application, the synthesis of selenocysteine and selenotreonine derivatives has been accomplished.
已经开发出一种简单有效的方法,用于通过一锅法在碘化铟(I)介导下使氮丙啶开环并与二有机酰基二硒醚反应来合成手性β-硒代胺衍生物。作为应用,已经完成了硒代半胱氨酸和硒代苏氨酸衍生物的合成。