通过熊田、赫克和施蒂勒交叉偶联反应合成芴基低聚有机硼试剂。
Synthesis of fluorene-based oligomeric organoboron reagents via Kumada, Heck, and Stille cross-coupling reactions.
作者信息
Zhang Xiaojie, Tian Hongkun, Liu Qin, Wang Lixiang, Geng Yanhou, Wang Fosong
机构信息
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Graduate School of Chinese Academy of Sciences, Changchun 130022, PR China.
出版信息
J Org Chem. 2006 May 26;71(11):4332-5. doi: 10.1021/jo0602470.
PMID:16709083
Abstract
Boronic pinacol ester group is not reactive in Kumada, Heck and Stille coupling reaction conditions. Fluorene-based sophisticated organoboron compounds were synthesized by means of Palladium catalyzed Kumada, Heck and Stille cross-coupling reactions from halofluorenyl boronic esters.
摘要
硼酸频哪醇酯基团在 Kumada、Heck 和 Stille 偶联反应条件下不具有反应活性。基于芴的复杂有机硼化合物是通过钯催化的 Kumada、Heck 和 Stille 交叉偶联反应，由卤代芴基硼酸酯合成的。
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