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苋菜水溶液在活性炭纤维上的电化学降解

Electrochemical degradation of amaranth aqueous solution on ACF.

作者信息

Fan Li, Zhou Yanwei, Yang Weishen, Chen Guohua, Yang Fenglin

机构信息

School of Material Science & Engineering, Beijing University of Aeronautics and Astronautics, Beijing 100083, China.

出版信息

J Hazard Mater. 2006 Sep 21;137(2):1182-8. doi: 10.1016/j.jhazmat.2006.04.008. Epub 2006 Apr 19.

Abstract

The degradation of Amaranth, a kind of azo dye, has been studied under galvanostatic model with activated carbon fiber (ACF) electrode in aqueous solution with electrochemical method. The ACF was used as anode and cathode, respectively for the decolorization process. The onset oxidation potential and reduction potential for Amaranth on ACF were respectively ascertained at 0.6 and -0.4 V. During the range of -1.1 to 0.50 mA cm(-2), the decolorization was clarified into three processes as electroreduction, adsorption and electrooxidation. There were little contributions to the color and COD removals for the process of adsorption. The color removal can be up to 99% when the current density was 0.50 mA cm(-2). The maximum COD removal was 52% for the process of electrooxidation. Hundred percent color removal was obtained when the current density of -1.0 mA cm(-2) was applied. The maximum COD removal was 62% for the electroreduction. The COD removal results from the adsorption of products for the decolorization process of electrooxidation or electroreduction.

摘要

采用电化学方法,在恒电流模式下,以活性炭纤维(ACF)电极研究了水溶液中偶氮染料苋菜红的降解情况。在脱色过程中,ACF分别用作阳极和阴极。确定了苋菜红在ACF上的起始氧化电位和还原电位分别为0.6 V和 -0.4 V。在 -1.1至0.50 mA cm⁻²范围内,脱色过程可分为电还原、吸附和电氧化三个过程。吸附过程对颜色和化学需氧量(COD)去除的贡献很小。当电流密度为0.50 mA cm⁻²时,脱色率可达99%。电氧化过程中COD的最大去除率为52%。当施加 -1.0 mA cm⁻²的电流密度时,脱色率达到100%。电还原过程中COD的最大去除率为62%。COD的去除是电氧化或电还原脱色过程中产物吸附的结果。

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