Mikami Koichi, Wakabayashi Kazuki, Yusa Yukinori, Aikawa Kohsuke
Department of Applied Chemistry, Tokyo Institute of Technology, Tokyo, 152-8552, Japan.
Chem Commun (Camb). 2006 Jun 14(22):2365-7. doi: 10.1039/b517585b. Epub 2006 May 3.
The chirality of an achiral benzophenone-based rhodium complex can be controlled by chiral diamines to afford significantly high enantioselectivity in the catalytic asymmetric transfer hydrogenation of ketones (up to 99% ee, 99% yield).
一种基于二苯甲酮的非手性铑配合物的手性可通过手性二胺来控制，从而在酮的催化不对称转移氢化反应中实现显著的高对映选择性（对映体过量高达99%，产率99%）。
