离子液体中的格氏试剂。
Grignard reagents in ionic liquids.
作者信息
Law Man Chun, Wong Kwok-Yin, Chan Tak Hang
机构信息
Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hong Hum, Hong Kong, China.
出版信息
Chem Commun (Camb). 2006 Jun 21(23):2457-9. doi: 10.1039/b602718k. Epub 2006 May 3.
DOI:10.1039/b602718k
PMID:16758014
Abstract
Grignard reagents were generated from magnesium and organic iodides in the ionic liquid n-butylpyridinium tetrafluoroborate, [bpy][BF4], and they showed different reactivity from classical Grignard reagents in organic solvents.
摘要
格氏试剂由镁和有机碘化物在离子液体四氟硼酸正丁基吡啶鎓（[bpy][BF4]）中生成，并且它们与在有机溶剂中的经典格氏试剂表现出不同的反应活性。
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