通过碘-铜交换直接制备带有醛官能团的有机金属铜化合物。
Direct preparation of copper organometallics bearing an aldehyde function via an iodine-copper exchange.
作者信息
Yang Xiaoyin, Knochel Paul
机构信息
Department Chemie, Ludwig-Maximilians-Universität München, Butenandtstr. 5-13, Haus F, 81377 München, Germany.
出版信息
Chem Commun (Camb). 2006 Jun 21(23):2486-8. doi: 10.1039/b604259g. Epub 2006 May 3.
DOI:10.1039/b604259g
PMID:16758024
Abstract
The iodine-copper exchange reaction allows the direct preparation of various aryl, heteroaryl and alkenyl cuprates bearing a formyl group, thus allowing a direct synthesis of polyfunctional aldehydes without the need of protecting groups or an additional oxidation step.
摘要
碘-铜交换反应可直接制备各种带有甲酰基的芳基、杂芳基和烯基铜酸盐，从而无需保护基团或额外的氧化步骤即可直接合成多官能醛。
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