一种用于甲醇合成的胶体ZnO/Cu纳米催化剂。
A colloidal ZnO/Cu nanocatalyst for methanol synthesis.
作者信息
Schröter Marie Katrin, Khodeir Lamma, van den Berg Maurits W E, Hikov Todor, Cokoja Mirza, Miao Shaojun, Grünert Wolfgang, Muhler Martin, Fischer Roland A
机构信息
Anorganische Chemie II, Ruhr-Universität Bochum, Universitätsstrasse 150, 44780, Bochum, Germany.
出版信息
Chem Commun (Camb). 2006 Jun 21(23):2498-500. doi: 10.1039/b602261h. Epub 2006 May 5.
DOI:10.1039/b602261h
PMID:16758028
Abstract
Free-standing, ZnO surface decorated Cu nanoparticles of 1-3 nm size were obtained by sequential co-pyrolysis of [Cu(OCHMeCH2NMe2)2] and ZnEt2 in squalane in the absence of additional surfactants and proved to be highly active quasi homogeneous catalysts for methanol synthesis from CO and H2.
摘要
通过在角鲨烷中依次共热解[Cu(OCHMeCH2NMe2)2]和ZnEt2，在没有额外表面活性剂的情况下获得了尺寸为1-3纳米的独立式、ZnO表面修饰的铜纳米颗粒，并且证明这些颗粒是用于由CO和H2合成甲醇的高活性准均相催化剂。
相似文献
1
A colloidal ZnO/Cu nanocatalyst for methanol synthesis.一种用于甲醇合成的胶体ZnO/Cu纳米催化剂。
Chem Commun (Camb). 2006 Jun 21(23):2498-500. doi: 10.1039/b602261h. Epub 2006 May 5.
2
In situ synthesis of Cu nanocatalysts on ZnO whiskers embedded in a microstructured paper composite for autothermal hydrogen production.原位合成嵌入微结构纸复合材料中的ZnO晶须上的铜纳米催化剂用于自热制氢。
Chem Commun (Camb). 2008 Nov 21(43):5616-8. doi: 10.1039/b812216d. Epub 2008 Sep 26.
3
Kinetics of hydrogen production of methanol reformation using Cu/ZnO/Al2O3 catalyst.使用Cu/ZnO/Al₂O₃催化剂的甲醇重整制氢动力学
J Comb Chem. 2007 Nov-Dec;9(6):990-7. doi: 10.1021/cc070066r. Epub 2007 Sep 28.
4
Direct synthesis of ethanol from dimethyl ether and syngas over combined H-Mordenite and Cu/ZnO catalysts.在 H-Mordenite 和 Cu/ZnO 催化剂的共同作用下，由二甲醚和合成气直接合成乙醇。
ChemSusChem. 2010 Oct 25;3(10):1192-9. doi: 10.1002/cssc.201000109.
5
Effect of the components' interface on the synthesis of methanol over Cu/ZnO from CO2/H2: a microkinetic analysis based on DFT + U calculations.CO₂/H₂在Cu/ZnO上合成甲醇过程中组分界面的影响：基于DFT+U计算的微观动力学分析
Phys Chem Chem Phys. 2015 Mar 21;17(11):7317-33. doi: 10.1039/c4cp05518g.
6
Cobalt-modified mesoporous MgO, ZrO2, and CeO2 oxides as catalysts for methanol decomposition.钴改性的介孔氧化镁、氧化锆和二氧化铈氧化物作为甲醇分解的催化剂。
J Colloid Interface Sci. 2009 May 1;333(1):277-84. doi: 10.1016/j.jcis.2008.12.070. Epub 2009 Feb 11.
7
The growth of Co:ZnO/ZnO core/shell colloidal quantum dots: changes in nanocrystal size, concentration and dopant coordination.钴掺杂氧化锌/氧化锌核壳胶体量子点的生长：纳米晶体尺寸、浓度和掺杂剂配位的变化
Chemphyschem. 2008 Feb 22;9(3):484-91. doi: 10.1002/cphc.200700753.
8
Tuning supported catalyst reactivity with dendrimer-templated Pt-Cu nanoparticles.通过树枝状大分子模板化的铂铜纳米颗粒调节负载型催化剂的反应活性。
J Phys Chem B. 2006 May 4;110(17):8606-12. doi: 10.1021/jp060833x.
9
Controlling ZnO morphology for improved methanol steam reforming reactivity.控制氧化锌形态以提高甲醇蒸汽重整反应活性。
Phys Chem Chem Phys. 2008 Sep 28;10(36):5584-90. doi: 10.1039/b800009c. Epub 2008 Jul 23.
10
Organometallics meet colloid chemistry: a case study in three phases based on molecular carbonyl precursors containing zinc and manganese.有机金属化合物与胶体化学的交汇：基于含锌和锰的分子羰基前体的三相案例研究
J Am Chem Soc. 2007 Jan 17;129(2):371-5. doi: 10.1021/ja0659626.
Zotero 插件