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Ferro- and antiferromagnetic interactions in face-sharing trioctahedral Ni(II)Mn(II)Ni(II) and Ni(II)Fe(III)Ni(II) complexes with the same 1-5/2-1 spin system.

作者信息

Kobayashi Tamami, Yamaguchi Tomoka, Ohta Hiromi, Sunatsuki Yukinari, Kojima Masaaki, Re Nazzareno, Nonoyama Matsuo, Matsumoto Naohide

机构信息

Department of Chemistry, Faculty of Science, Okayama University, Tsushima-naka 3-1-1, Okayama 700-8530, Japan.

出版信息

Chem Commun (Camb). 2006 May 14(18):1950-2. doi: 10.1039/b517503h. Epub 2006 Apr 10.

DOI:10.1039/b517503h
PMID:16767246
Abstract

Two heterotrinuclear complexes, [Mn(II)(Ni(II)L)2].2CH3OH (where H3L = 1,1,1-tris(N-salicylideneaminomethyl)ethane) and [Fe(III)(Ni(II)L)2]NO3.C2H5OH, consisting of three face-sharing octahedra have been prepared; although these complexes have closely related structures and have the same 1-5/2-1 spin system, they show completely different magnetic interactions between the adjacent metal ions: ferromagnetic (Ni(II)-Mn(II)) and antiferromagnetic (Ni(II)-Fe(III)).

摘要

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