Gupta Arvinda K, Pardasani Deepak, Kanaujia Pankaj K, Tak Vijay, Dubey Devendra K
Vertox Laboratory, Defence Research and Development Establishment, Gwalior, India.
Rapid Commun Mass Spectrom. 2006;20(14):2115-9. doi: 10.1002/rcm.2569.
Gas chromatography/electron ionization mass spectrometry (GC/EI-MS) of N,N-dialkylaminoethyl-2-chlorides (DAAECls) and trimethylsilyl (TMS) derivatives of N,N-dialkylaminoethan-2-ols (DAAEAs) has been carried out. GC/EI-MS data of these compounds are of importance for verification of the Chemical Weapons Convention (CWC). Based on these EI mass spectra, generalized fragmentation routes are proposed that rationalize most of the characteristic ions.
已对N,N-二烷基氨基乙基-2-氯（DAAECls）和N,N-二烷基氨基乙醇（DAAEAs）的三甲基硅烷基（TMS）衍生物进行了气相色谱/电子电离质谱分析（GC/EI-MS）。这些化合物的GC/EI-MS数据对于《化学武器公约》（CWC）的核查具有重要意义。基于这些EI质谱图，提出了能使大多数特征离子合理化的通用裂解途径。
