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铜（II）与1-氨基环丙烷-1-羧酸酯的顺式和反式配合物在固态下自组装成离散的三聚体。

Self-assembly of cis and trans forms of the copper(II) complex with 1-aminocyclopropane-1-carboxylate into discrete trimers in the solid state.

作者信息

Judas Nenad, Raos Nenad

机构信息

Laboratory of General and Inorganic Chemistry, Department of Chemistry, Faculty of Science, University of Zagreb, Horvatovac 102a, HR-10000 Zagreb, Croatia.

出版信息

Inorg Chem. 2006 Jun 26;45(13):4892-4. doi: 10.1021/ic060780y.

DOI:10.1021/ic060780y
PMID:16780308
Abstract

A copper(II) complex with 1-aminocyclopropane-1-carboxylic acid assembles by apical Cu...O bonds and hydrogen-bonding interactions into discrete trimeric units that exhibit both cis and trans binding modes.

摘要

一种含有1-氨基环丙烷-1-羧酸的铜（II）配合物通过顶端的铜……氧键和氢键相互作用组装成离散的三聚体单元，这些单元呈现出顺式和反式结合模式。

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引用本文的文献

1
1-Aminocyclopropane-1-carboxylic acid oxidase: insight into cofactor binding from experimental and theoretical studies.1-氨基环丙烷-1-羧酸氧化酶：实验和理论研究揭示辅因子结合的结构基础。
J Biol Inorg Chem. 2012 Aug;17(6):939-49. doi: 10.1007/s00775-012-0910-3. Epub 2012 Jun 19.
2
Characterization of Cu(II)-ACC complexes and conversion of the bound ACC into ethylene in the presence of hydrogen peroxide. detection of a brown intermediate at low temperature.Cu(II)-ACC 配合物的特性以及在过氧化氢存在下将结合的 ACC 转化为乙烯。在低温下检测到一种棕色中间体。
Bioinorg Chem Appl. 2007;2007:43424. doi: 10.1155/2007/43424.