Campione M, Sassella A
Department of Materials Science and CNISM, Università di Milano Bicocca, Via Cozzi 53, I-20125 Milano, Italy.
J Chem Phys. 2006 Jun 14;124(22):224705. doi: 10.1063/1.2202327.
The diamagnetic response of tetracene is exploited to increase the in-plane orientation of thin films grown by organic molecular beam deposition, while applying a magnetic field of 0.2 T parallel to the surface of the silica and potassium hydrogen phthalate substrates. The combined spectroscopic analysis of the films in the UV/visible region and morphological investigation of their surface performed by atomic force microscopy demonstrate a substantial increment of the film order when the magnetic field is applied along the c axis of potassium hydrogen phthalate, in agreement with the anisotropic magnetic susceptibility of tetracene.
利用并四苯的抗磁响应来提高通过有机分子束沉积生长的薄膜的面内取向,同时在平行于二氧化硅和邻苯二甲酸氢钾基板表面施加0.2 T的磁场。通过紫外/可见区域对薄膜进行的联合光谱分析以及通过原子力显微镜对其表面进行的形态学研究表明,当磁场沿邻苯二甲酸氢钾的c轴施加时,薄膜的有序度显著增加,这与并四苯的各向异性磁化率一致。