Yin Chun-Yang, Mahmud Hilmi Bin, Shaaban Md Ghazaly
Faculty of Chemical Engineering, Universiti Teknologi MARA, 40450 Shah Alam, Selangor Darul Ehsan, Malaysia.
J Hazard Mater. 2006 Oct 11;137(3):1758-64. doi: 10.1016/j.jhazmat.2006.05.013. Epub 2006 May 11.
This paper presents the findings of a study on solidification/stabilization (S/S) of lead-contaminated soil using ordinary Portland cement (OPC) and rice husk ash (RHA). The effects of varying lead concentrations (in the form of nitrates) in soil samples on the physical properties of their stabilized forms, namely unconfined compressive strength (UCS), setting times of early mixtures and changes in crystalline phases as well as chemical properties such as leachability of lead, pH and alkalinity of leachates are studied. Results have indicated that usage of OPC with RHA as an overall binder system for S/S of lead-contaminated soils is more favorable in reducing the leachability of lead from the treated samples than a binder system with standalone OPC. On the other hand, partial replacement of OPC with RHA in the binder system has reduced the UCS of solidified samples.
本文介绍了一项关于使用普通硅酸盐水泥(OPC)和稻壳灰(RHA)对铅污染土壤进行固化/稳定化(S/S)处理的研究结果。研究了土壤样品中不同铅浓度(以硝酸盐形式)对其稳定化形式的物理性质的影响,即无侧限抗压强度(UCS)、早期混合物的凝结时间、晶相变化以及化学性质,如铅的浸出性、浸出液的pH值和碱度。结果表明,与单独使用OPC的粘结剂体系相比,使用OPC与RHA作为铅污染土壤S/S处理的整体粘结剂体系,更有利于降低处理后样品中铅的浸出性。另一方面,在粘结剂体系中用RHA部分替代OPC降低了固化样品的UCS。