Li Jiangshan, Poon Chi Sun
Department of Civil and Environmental Engineering, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong.
Department of Civil and Environmental Engineering, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong.
Chemosphere. 2017 Apr;173:143-152. doi: 10.1016/j.chemosphere.2017.01.065. Epub 2017 Jan 12.
The proper treatment of lead (Pb) contaminated soils and incinerated sewage sludge ash (ISSA) has become an environmental concern. In this study, ordinary Portland cement (OPC) and blended OPC containing incinerated sewage sludge ash (ISSA) were used to solidify/stabilize (S/S) soils contaminated with different concentrations of Pb. After curing for 7 and 28 d, the S/S soils were subjected to a series of strength, leaching and microscopic tests. The results showed that replacement of OPC by ISSA significantly reduced the unconfined compressive strength (UCS) of S/S soils and leached Pb. In addition, the leaching of Pb from the monolithic samples was diffusion controlled, and increasing the ISSA addition in the samples led to a lower diffusion coefficient and thus an increase in the feasibility for "controlled utilization" of S/S soils. Furthermore, the proposed S/S method significantly decreased the amount of Pb associated with carbonates and increased the amount of organic and residual Pb in S/S soils, reflecting that the risk of Pb contaminated soils can be effectively mitigated by the incorporating of ISSA. Overall, the leachability of Pb was controlled by the combined effect of adsorption, encapsulation or precipitation in the S/S soils.
铅(Pb)污染土壤和焚烧污水污泥灰(ISSA)的合理处理已成为一个环境问题。在本研究中,普通硅酸盐水泥(OPC)和含有焚烧污水污泥灰(ISSA)的混合OPC被用于固化/稳定化(S/S)不同浓度Pb污染的土壤。养护7天和28天后,对S/S土壤进行了一系列强度、浸出和微观测试。结果表明,用ISSA替代OPC显著降低了S/S土壤的无侧限抗压强度(UCS)和浸出的Pb。此外,整块样品中Pb的浸出受扩散控制,增加样品中ISSA的添加量会导致扩散系数降低,从而增加S/S土壤“受控利用”的可行性。此外,所提出的S/S方法显著降低了与碳酸盐结合的Pb量,并增加了S/S土壤中有机和残留Pb的量,这表明通过掺入ISSA可以有效降低Pb污染土壤的风险。总体而言,S/S土壤中Pb的浸出性受吸附、包裹或沉淀的综合作用控制。