聚合物包裹铂（PI Pt）催化剂的实际获取及其在氢化反应中的应用。
Practical access to the polymer incarcerated platinum (PI Pt) catalyst and its application to hydrogenation.
作者信息
Miyazaki Yoji, Hagio Hiroyuki, Sugiura Masaharu, Kobayashi Shū
机构信息
Graduate School of Pharmaceutical Sciences, The University of Tokyo, Astellas Pharma Inc., Hongo, Bunkyo-ku, Japan.
出版信息
Org Biomol Chem. 2006 Jul 7;4(13):2529-31. doi: 10.1039/b605288f. Epub 2006 May 31.
DOI:10.1039/b605288f
PMID:16791314
Abstract
Polymer incarcerated platinum catalysts (PI Pt) were conveniently prepared from PtCl(2)(COD) or H(2)PtCl(6).6H(2)O and styrene copolymers via reduction of the Pt sources with triethylamine, coacervation, and cross-linking. The Pt catalysts have been successfully applied to catalytic hydrogenation including saturation of heterocyclic compounds.
摘要
聚合物包封铂催化剂（PI Pt）可通过用三乙胺还原铂源、凝聚和交联，由PtCl(2)(COD)或H(2)PtCl(6).6H(2)O与苯乙烯共聚物方便地制备而成。这些铂催化剂已成功应用于催化氢化反应，包括杂环化合物的饱和反应。
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