用于炔烃催化部分加氢反应的连续流动过程。
Continuous-flow processes for the catalytic partial hydrogenation reaction of alkynes.
作者信息
Moreno-Marrodan Carmen, Liguori Francesca, Barbaro Pierluigi
机构信息
Consiglio Nazionale delle Ricerche, Istituto di Chimica dei Composti Organo Metallici, Via Madonna del Piano 10, 50019 Sesto Fiorentino, Firenze, Italy.
出版信息
Beilstein J Org Chem. 2017 Apr 20;13:734-754. doi: 10.3762/bjoc.13.73. eCollection 2017.
The catalytic partial hydrogenation of substituted alkynes to alkenes is a process of high importance in the manufacture of several market chemicals. The present paper shortly reviews the heterogeneous catalytic systems engineered for this reaction under continuous flow and in the liquid phase. The main contributions appeared in the literature from 1997 up to August 2016 are discussed in terms of reactor design. A comparison with batch and industrial processes is provided whenever possible.
将取代炔烃催化部分加氢制烯烃是几种市场化学品制造过程中非常重要的一个过程。本文简要综述了为该反应设计的连续流动液相非均相催化体系。本文从反应器设计的角度讨论了1997年至2016年8月期间文献中出现的主要贡献。只要有可能，就会与间歇和工业过程进行比较。
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