氟鲁凝胶：超临界二氧化碳中用于需氧醇氧化的多功能催化剂。
FluoRuGel: a versatile catalyst for aerobic alcohol oxidation in supercritical carbon dioxide.
作者信息
Ciriminna Rosaria, Campestrini Sandro, Pagliaro Mario
机构信息
Istituto per lo Studio dei Materiali Nanostrutturati, CNR, Palermo, Italy.
出版信息
Org Biomol Chem. 2006 Jul 7;4(13):2637-41. doi: 10.1039/b604663k. Epub 2006 Jun 7.
DOI:10.1039/b604663k
PMID:16791328
Abstract
FluoRuGel--a hybrid fluorinated silica glass doped with TPAP (tetra-n-propylammonium perruthenate)--is a versatile catalyst for the aerobic oxidation of different alcohols in dense phase CO(2) with marked stabilization and activity enhancement of perruthenate upon its confinement in the sol-gel fluorinated silica matrix. A brief competitive analysis shows large potential rewards.
摘要
氟凝胶——一种掺杂了TPAP（四正丙基过钌酸铵）的混合氟化硅玻璃——是一种多功能催化剂，用于在致密相CO₂中对不同醇类进行需氧氧化，当钌酸盐被限制在溶胶-凝胶氟化硅基质中时，其稳定性和活性显著增强。简要的竞争分析显示出巨大的潜在回报。
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