Chen Duohong, Zeng Xiangying, Sheng Yanqing, Bi Xinhui, Gui Hongyan, Sheng Guoying, Fu Jiamo
Guangdong Key Laboratory of Environment and Resources, State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, Guangdong Province, China.
Chemosphere. 2007 Jan;66(2):252-8. doi: 10.1016/j.chemosphere.2006.05.024. Epub 2006 Jun 30.
Polycyclic musks [cashmeran (DPMI), celestolide (ADBI), phantolide (AHMI), traseolide (ATII), tonalide (AHTN) and galaxolide (HHCB)] in the air, wastewater, sludge samples of a typical cosmetic plant were analyzed. DPMI, ADBI, HHCB and AHTN were found in all samples, and ATII was not found in any sample. HHCB and AHTN were the major components in all samples. The polycyclic musk concentrations were very high in the air of the cosmetic plant, and polycyclic musks were mostly contained in the gas phase at the percentage of 86.35-97.70%. Average polycyclic musk concentrations in effluent were high, and ranged from 0.62 to 32.06 microgl-1. The removal efficiency during the active sludge wastewater treatment was also high, resulting from the adsorption of those compounds into the sludge. So the polycyclic musk concentrations were very high in the primary sludge and second sludge, and ranged from 1.78 to 92.45 mgkg-1 (dry), and from 2.87 to 65.67 mgkg-1 (dry), respectively. Results suggested that the sludge needed to be further treated to make polycyclic musks less influence to the environment.
对一家典型化妆品厂的空气、废水、污泥样本中的多环麝香(佳乐麝香(DPMI)、吐纳麝香(ADBI)、粉檀麝香(AHMI)、内型十三烷内酯(ATII)、葵子麝香(AHTN)和 galaxolide(HHCB))进行了分析。在所有样本中均检测到 DPMI、ADBI、HHCB 和 AHTN,未在任何样本中检测到 ATII。HHCB 和 AHTN 是所有样本中的主要成分。化妆品厂空气中的多环麝香浓度非常高,多环麝香大多存在于气相中,占比为 86.35 - 97.70%。废水的平均多环麝香浓度较高,范围为 0.62 至 32.06 μg/L。活性污泥废水处理过程中的去除效率也很高,这是由于这些化合物吸附到污泥中。因此,初沉污泥和二沉污泥中的多环麝香浓度非常高,分别为 1.78 至 92.45 mg/kg(干重)和 2.87 至 65.67 mg/kg(干重)。结果表明,污泥需要进一步处理,以使多环麝香对环境的影响更小。