High-temperature measurements of the reactions of OH with toluene and acetone.

The reaction of hydroxyl [OH] radicals with toluene [C6H5CH3] was studied at temperatures between 911 and 1389 K behind reflected shock waves at pressures of approximately 2.25 atm. OH radicals were generated by rapid thermal decomposition of shock-heated tert-butyl hydroperoxide [(CH3)3-CO-OH], and monitored by narrow-line width ring dye laser absorption of the well-characterized R1(5) line of the OH A-X (0,0) band near 306.7 nm. OH time histories were modeled by using a comprehensive toluene oxidation mechanism. Rate constants for the reaction of C6H5CH3 with OH were extracted by matching modeled and measured OH concentration time histories in the reflected shock region. Detailed error analyses yielded an uncertainty estimate of +/-30% at 1115 K for the rate coefficient of this reaction. The current high-temperature data were fit with the lower temperature measurements of Tully et al. [J. Phys. Chem. 1981, 85, 2262-2269] to the following two-parameter form, applicable over 570-1389 K: k3 = (1.62 x 10(13)) exp(-1394/T [K]) [cm3 mol(-1) s(-1)]. The reaction between OH radicals and acetone [CH3COCH3] was one of the secondary reactions encountered in the toluene + OH experiments. Direct high-temperature measurements of this reaction were carried out at temperatures ranging from 982 to 1300 K in reflected shock wave experiments at an average total pressure of 1.65 atm. Uncertainty limits were estimated to be +/-25% at 1159 K. A two-parameter fit of the current data yields the following rate expression: k6 = (2.95 x 10(13)) exp(-2297/T [K]) [cm3 mol(-1) s(-1)].