离子液体N-甲基-N-丙基吡咯烷双（三氟甲磺酰）亚胺及其与LiN(SO2CF3)2混合物的拉曼光谱研究
Raman investigation of the ionic liquid N-methyl-N-propylpyrrolidinium bis(trifluoromethanesulfonyl)imide and its mixture with LiN(SO2CF3)2.
作者信息
Castriota M, Caruso T, Agostino R G, Cazzanelli E, Henderson W A, Passerini S
机构信息
LiCryl-INFM (Liquid Crystal Regional Laboratory), c/o Department of Physics, University of Calabria, Via P. Bucci Cubo 31C, I-87036 Rende (CS), Italy.
出版信息
J Phys Chem A. 2005 Jan 13;109(1):92-6. doi: 10.1021/jp046030w.
A preliminary Raman investigation of the ionic liquid N-methyl-N-propylpyrrolidinium bis(trifluoromethanesulfonyl)imide (PYR(13)TFSI) and its 2/1 complex with the lithium salt LiN(SO(2)CF(3))(2) is reported. The study was performed over a temperature range extending from -100 to +60 degrees C, i.e., with PYR(13)TFSI in the crystalline and melt states. For comparison purposes, the study was extended to PYR(13)I, which is the precursor used in the synthesis of PYR(13)TFSI.
报道了对离子液体N-甲基-N-丙基吡咯烷鎓双（三氟甲磺酰）亚胺（PYR(13)TFSI）及其与锂盐LiN(SO(2)CF(3))(2)的2/1配合物的初步拉曼研究。该研究在-100至+60摄氏度的温度范围内进行，即PYR(13)TFSI处于结晶态和熔融态。为作比较，该研究扩展至PYR(13)I，其为合成PYR(13)TFSI所用的前体。
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