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金属纳米壳的内部电场密度

Internal electric field densities of metal nanoshells.

作者信息

Schelm Stefan, Smith Geoff B

机构信息

Department of Applied Physics, University of Technology, Sydney, P.O. Box 123 Broadway, 2007 NSW, Australia. stefan.schelm@ uts.edu.au

出版信息

J Phys Chem B. 2005 Feb 10;109(5):1689-94. doi: 10.1021/jp0450686.

Abstract

The internal field patterns for gold shells filled with the same material as the surrounding medium are calculated with Mie theory and in the quasistatic approximation and their properties compared to the response of homogeneous spheres and metallic rings. One major difference between the sphere and shell case is that the areas of highest field enhancement in metallic shells are located perpendicular to the incident polarization, whereas for metallic spheres they are along the polarization direction. Recent results based on the discrete dipole approximation (DDA) are shown to be misleading, which might be due to the use of a too coarse grid size. We also show that the type of resonance and the associated internal field pattern (low or high energy) has a strong impact on the external fields.

摘要

利用米氏理论并在准静态近似下计算了填充与周围介质相同材料的金壳的内部场模式,并将其性质与均匀球体和金属环的响应进行了比较。球体和壳情况之间的一个主要区别是,金属壳中场增强最高的区域位于垂直于入射偏振的方向,而对于金属球体,它们沿着偏振方向。基于离散偶极近似(DDA)的最新结果被证明具有误导性,这可能是由于使用了过于粗糙的网格尺寸。我们还表明,共振类型和相关的内部场模式(低能量或高能量)对外部场有强烈影响。

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