Kim Sunhee, Byl Oleg, Yates John T
Department of Chemistry, Surface Science Center, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, USA.
J Phys Chem B. 2005 Apr 7;109(13):6331-3. doi: 10.1021/jp0407369.
The adsorption of triethylenediamine (TEDA) on Lewis acid (Al(3+)) sites of the highly dehydroxylated Al(2)O(3) surface has been observed by FT-IR spectroscopy. This was done by monitoring the competitive adsorption of TEDA and CO on the Al(3+) sites. A stoichiometric replacement of Al(3+)-CO species was observed as Al(3+)-TEDA surface species were formed.
通过傅里叶变换红外光谱法观察到三乙烯二胺（TEDA）在高度脱羟基的Al₂O₃表面的路易斯酸（Al³⁺）位点上的吸附。这是通过监测TEDA和CO在Al³⁺位点上的竞争性吸附来实现的。当形成Al³⁺-TEDA表面物种时，观察到Al³⁺-CO物种的化学计量取代。
