Yang Jeff H, Henao Juan D, Raphulu Mpfunzeni C, Wang Yingmin, Caputo Tiziana, Groszek A J, Kung Mayfair C, Scurrell Michael S, Miller Jeffrey T, Kung Harold H
Department of Chemical and Biological Engineering and Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208-3120, USA.
J Phys Chem B. 2005 May 26;109(20):10319-26. doi: 10.1021/jp050818c.
Changes in a Au/TiO(2) catalyst during the activation process from an as-prepared state, consisting of supported AuO(x)(OH)(4-2x)(-) species, were monitored with X-ray absorption spectroscopy and FTIR spectroscopy, complemented with XPS, microcalorimetry, and TEM characterization. When the catalyst was activated with H(2) pulses at 298 K, there was an induction period when little changes were detected. This was followed by a period of increasing rate of reduction of Au(3+) to Au(0), before the reduction rate decreased until the sample was fully reduced. A similar trend in the activation process was observed if CO pulses at 273 K or a steady flow of CO at about 240 K was used to activate the sample. With both activation procedures, the CO oxidation activity of the catalyst at 195 K increased with the degree of reduction up to 70% reduction, and decreased slightly beyond 80% reduction. The results were consistent with metallic Au being necessary for catalytic activity.
