Song Wenhui, Tu Houjie, Goldbeck-Wood Gerhard, Windle Alan H
Department of Materials Science and Metallurgy, Cambridge University, Pembroke Street, Cambridge CB2 3QZ, UK.
J Phys Chem B. 2005 Oct 20;109(41):19234-41. doi: 10.1021/jp052919g.
In this work, disclination interaction behavior in relation to Frank elastic constant anisotropy in nematics has been studied. A large number of (+(1/2), -(1/2)) disclination pairs are revealed by spontaneous band texture in a semiflexible copolyester. The pairs show no preferential relative orientation, with the intervening fields showing intermediate patterns. A two-dimensional tensor lattice model considering unequal elastic constants is applied to simulate the interaction behavior and patterns of disclination pairs in the presence of elastic anisotropy. Scaling laws for disclination density rho(t) as a function of time step t with different elastic anisotropy are obtained as t(-nu). The value of the exponent nu decreases as elastic anisotropy is increased. Obviously, elastic anisotropy slows the texture coarsening. The simulations also show that angular forces arise in the presence of elastic anisotropy and change the patterns of pairs during the texture coarsening. When disclination density is considerably decreased, some +(1/2) disclinations start to rotate to the energetically favored patterns depending on the sign of the elastic anisotropy. As a result of the disclination rotation, the distribution of patterns of pairs continues to change during the annihilation. However, disclination pairs are influenced not only by elastic anisotropy but also by disclination interaction during the whole annihilation. Therefore, in a real system, the dependence of pairs on elastic anisotropy is not as strong as the theoretical prediction for an isolated pair, and the full pattern range of disclination pairs can be observed.
