Wu Qiang, Hu Zheng, Liu Chun, Wang Xizhang, Chen Yi, Lu Yinong
Key Laboratory of Mesoscopic Chemistry of MOE and Jiangsu Provincial Laboratory for NanoTechnology, Department of Chemistry, Nanjing University, Nanjing 210093, China.
J Phys Chem B. 2005 Oct 27;109(42):19719-22. doi: 10.1021/jp053058e.
Gallium phosphide nanotubes with zinc blende structure were synthesized for the first time. The as-prepared GaP nanotubes are polycrystalline with diameters of 30-120 nm and occasionally partially filled. The growth has been reasonably proposed to follow vapor-liquid-solid (VLS) mechanism. The integration of the nanotubular structure with the unique intrinsic semiconducting properties of GaP might bring GaP nanotubes some novel optical and electronic properties and applications.
首次合成了具有闪锌矿结构的磷化镓纳米管。所制备的磷化镓纳米管为多晶，直径为30 - 120纳米，偶尔会部分填充。合理推测其生长遵循气-液-固（VLS）机制。纳米管结构与磷化镓独特的本征半导体特性的结合可能会赋予磷化镓纳米管一些新颖的光学和电子特性及应用。
