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Silver clusters on silver sulfide nanocrystals: synthesis and behavior after electron beam irradiation.

作者信息

Motte L, Urban J

机构信息

Laboratoire LM2N, URA CNRS 1662, Université P. et M. Curie, 4 Place Jussieu, Paris, France.

出版信息

J Phys Chem B. 2005 Nov 24;109(46):21499-501. doi: 10.1021/jp0542322.

Abstract

Nanocomposite crystals, (Ag)(x)(Ag(2)S)(y) with x < y, are synthesized in micellar media. The generation of Ag clusters on Ag(2)S nanocrystals is attributed to the reduction of mobile Ag(+) ions in the Ag(2)S nanocrystals by sulfur derivatives. The proportions in the composite material can be modulated by electron beam irradiation. Using dodecanethiol as surface passivating agent, 2D self-organizations of these nanocomposite crystals are produced.

摘要

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