通过配位作用构建分子结构：具有设计模块的纳米级六边形金属树枝状大分子的自组装

Molecular architecture via coordination: self-assembly of nanoscale hexagonal metallodendrimers with designed building blocks.

作者信息

Yang Hai-Bo, Das Neeladri, Huang Feihe, Hawkridge Adam M, Muddiman David C, Stang Peter J

机构信息

Department of Chemistry, University of Utah, 315 South 1400 East, RM 2020, Salt Lake City, Utah 84112, USA.

出版信息

J Am Chem Soc. 2006 Aug 9;128(31):10014-5. doi: 10.1021/ja063377z.

DOI:10.1021/ja063377z

PMID:16881621

Abstract

The first self-assembly of nanoscale metallodendrimers that have a hexagonal cavity as a core via the directional-bonding approach is reported. All metallodendrimers were characterized by multinuclear NMR (1H and 31P), mass spectrometry (ESI-MS and ESI-FT-ICR), and elemental analysis.

摘要

报道了通过定向键合方法首次自组装以六边形空腔为核心的纳米级金属树枝状大分子。所有金属树枝状大分子均通过多核核磁共振（1H和31P）、质谱（电喷雾电离质谱和电喷雾电离傅里叶变换离子回旋共振质谱）和元素分析进行表征。