Litto R, Hayes R E, Liu B
Department of Chemical and Materials Engineering, University of Alberta, Edmonton, Alta., Canada T6G 2G6.
J Environ Manage. 2007 Aug;84(3):347-61. doi: 10.1016/j.jenvman.2006.06.007. Epub 2006 Aug 7.
Fugitive methane emissions account for about 50% of the greenhouse gas (GHG) emissions from the Canadian conventional oil and gas sector. Sources include leaks in natural gas transmission facilities such as pipelines and compressor stations. There are three sources of methane emissions in a compressor station. The first is emissions resulting from incomplete combustion in the engine; the second is leaks in valves, flanges and other equipment in the building; and the third results from instrument venting. Fugitive methane emissions may be in low concentration relative to air, and thus cannot be destroyed by conventional combustion (below flammability limits of about 5-16%). The present study investigates the feasibility of capturing methane emissions from a compressor station. Computer modelling of the flow patterns of lean methane emissions inside the building is used to show the influence of doors, vents and leak location. Simulations show that for a typical building most fugitive methane exits through the ridge vent provided that the main doors remain closed. When the extraction rate through the ridge vent is controlled, the methane concentration is at acceptable levels for destruction in a catalytic flow reverse reactor, that is, in the range of 0.1-1% by volume.
逃逸性甲烷排放约占加拿大常规石油和天然气行业温室气体(GHG)排放的50%。排放源包括天然气输送设施(如管道和压缩机站)的泄漏。压缩机站有三个甲烷排放源。第一个是发动机内不完全燃烧产生的排放;第二个是建筑物内阀门、法兰和其他设备的泄漏;第三个是仪器排气产生的排放。相对于空气而言,逃逸性甲烷排放可能浓度较低,因此无法通过常规燃烧方式销毁(低于约5%-16%的可燃极限)。本研究调查了从压缩机站捕获甲烷排放的可行性。通过对建筑物内贫甲烷排放气流模式进行计算机建模,以显示门、通风口和泄漏位置的影响。模拟结果表明,对于典型建筑物,只要主门保持关闭,大部分逃逸性甲烷会通过屋脊通风口排出。当通过屋脊通风口的抽取速率得到控制时,甲烷浓度处于催化逆流反应器中可接受的销毁水平,即体积分数在0.1%-1%的范围内。