Wan Michael T, Kuo Jen-ni, McPherson Brad, Pasternak John
Environmental Stewardship Branch, Commercial Chemicals and Environmental Emergencies Section, Environment Canada, Pacific and Yukon, 201-401 Burrard St. Vancouver V6C 3S5.
J Environ Sci Health B. 2006;41(6):855-67. doi: 10.1080/03601230600805931.
Crop soils, ditch sediments and water flowing from several Lower Fraser River (LFR) farm areas of British Columbia, Canada, to salmon tributary streams of that river were sampled in 2004-2005 to quantify for residues of triazine [atrazine, desethylatrazine (a transformation product of atrazine), propazine, and simazine] and metolachlor (a chloroacetamide) herbicides. Average concentrations [microg kg-1 dry weight (d.w.)] of triazine (10,110) and metolachlor (8,910) herbicides detected in crop soils at the start (May 2004, 2005) of the growing season were about 17 and 6 times, respectively, higher than those found for both herbicide groups during (June-Sept, 2004, 2005) the growing season. In contrast, mean concentrations (microg L-1) of triazines (0.092) and metolachlor (0.014) in permanent ditches adjacent to farms were about 7 and 28 times, respectively, lower at the start than during the growing season. Both herbicide groups in ditch sediments were detected only during the growing season at concentrations averaging about 315 microg kg-1 d.w. The risk potential of these herbicides for non-target aquatic organisms inhabiting permanent farm ditches contiguous to tributary streams of the LFR during the growing season is evaluated and discussed.
2004年至2005年期间,对加拿大不列颠哥伦比亚省弗雷泽河下游(LFR)几个农场地区的农田土壤、沟渠沉积物以及从这些地区流入该河鲑鱼支流的水流进行了采样,以量化三嗪类除草剂[阿特拉津、去乙基阿特拉津(阿特拉津的一种转化产物)、扑灭通和西玛津]和异丙甲草胺(一种氯乙酰胺类除草剂)的残留量。在生长季开始时(2004年5月、2005年5月),农田土壤中检测到的三嗪类除草剂(10,110)和异丙甲草胺(8,910)的平均浓度[微克/千克干重(d.w.)]分别比生长季期间(2004年6月至9月、2005年6月至9月)这两类除草剂的浓度高出约17倍和6倍。相比之下,农场附近永久性沟渠中三嗪类除草剂(0.092)和异丙甲草胺(0.014)的平均浓度[微克/升]在生长季开始时分别比生长季期间低约7倍和28倍。仅在生长季期间在沟渠沉积物中检测到这两类除草剂,平均浓度约为315微克/千克干重。对这些除草剂在生长季期间对居住在与LFR支流相邻的永久性农场沟渠中的非靶标水生生物的潜在风险进行了评估和讨论。