一种对烯烃分子内氢胺化反应具有更高反应活性的新型均相锌配合物。
A new homogeneous zinc complex with increased reactivity for the intramolecular hydroamination of alkenes.
作者信息
Dochnahl Maximilian, Pissarek Jens-Wolfgang, Blechert Siegfried, Löhnwitz Karolin, Roesky Peter W
机构信息
Technische Universität Berlin, Institut für Chemie, Strasse des 17. Juni 135, 10623 Berlin, Germany.
出版信息
Chem Commun (Camb). 2006 Aug 28(32):3405-7. doi: 10.1039/b607597e. Epub 2006 Jul 24.
DOI:10.1039/b607597e
PMID:16896476
Abstract
The new zinc compound N-cyclohexyl-2-(cyclohexylamino)troponiminate zinc methyl, [(Cy)2ATI]ZnMe, was synthesized and showed a superior reactivity in the intramolecular hydroamination reaction of non-activated alkenes compared to previously reported homogeneous zinc complexes.
摘要
新型锌化合物N-环己基-2-(环己基氨基)环丙烯亚胺锌甲基盐，即[(Cy)2ATI]ZnMe，已被合成，并且与先前报道的均相锌配合物相比，在未活化烯烃的分子内氢胺化反应中表现出更高的反应活性。
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