膦-烯烃配体：一种通往催化活性铑配合物的简便脱氢途径。
Phosphine-olefin ligands: a facile dehydrogenative route to catalytically active rhodium complexes.
作者信息
Douglas Thomas M, Le Nôtre Jérôme, Brayshaw Simon K, Frost Christopher G, Weller Andrew S
机构信息
Department of Chemistry, University of Bath, Bath, UK.
出版信息
Chem Commun (Camb). 2006 Aug 28(32):3408-10. doi: 10.1039/b608129k. Epub 2006 Jul 21.
DOI:10.1039/b608129k
PMID:16896477
Abstract
Facile, metal-mediated, (acceptorless) dehydrogenation of tricyclopentyl phosphine directly affords rhodium chelating phosphine-olefin complexes, some of which are catalytically active for 1,4-additions.
摘要
通过金属介导的（无受体）三环戊基膦直接脱氢反应可简便地得到铑螯合膦-烯烃配合物，其中一些对1,4-加成反应具有催化活性。
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