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苏伊士湾沉积物中可浸出重金属和总重金属的分布及统计分析

Distribution and statistical analysis of leachable and total heavy metals in the sediments of the Suez Gulf.

作者信息

el-Nemr Ahmed, Khaled Azza, el-Sikaily Amany

机构信息

Environmental Division, National Institute of Oceanography and Fisheries, Kayet Bay, El-Anfushy, Alexandria, Egypt.

出版信息

Environ Monit Assess. 2006 Jul;118(1-3):89-112. doi: 10.1007/s10661-006-0985-9.

Abstract

The concentrations of nine heavy metals (Cd, Co, Cr, Cu, Fe, Mn, Ni, Pd and Zn) in the labile and total fractions of muddy and sandy sediment samples collected from twelve sites in Suez Gulf during April 1999 were studied to evaluate the pollution status of the Suez Gulf. The enrichment factors (EF) for each element were calculated. There are extremely high concentrations of Cd, Ni, Pb and slightly concentration of Cr and Cu in both muddy and sandy sediments. The concentration of Zn was moderately high and can be considered as seriously contaminate Metal pollution index (MPI) shows high values ranged between 46 to 156 and 40 to 232 for both sandy and muddy sediments, respectively. Concentrations of heavy metals were normalized against iron for total fraction in both of sandy and muddy sediments. Principal component analysis (PCA) was studied on the data matrix obtained and represented three-factor model explaining 92.22% for labile and 88.82% for total fractions of muddy sediment. The main source of contamination is the offshore oil fields and industrial wastes. This is largely a result of ineffective and inefficient operation equipment, illegal discharge of dirty ballast water from tankers and lack of supervision and prosecution of offenders.

摘要

1999年4月,对从苏伊士湾12个地点采集的泥质和砂质沉积物样本的不稳定态和总量态中的9种重金属(镉、钴、铬、铜、铁、锰、镍、钯和锌)浓度进行了研究,以评估苏伊士湾的污染状况。计算了每种元素的富集因子(EF)。泥质和砂质沉积物中镉、镍、铅的浓度极高,铬和铜的浓度略高。锌的浓度中等偏高,可被视为受到严重污染。金属污染指数(MPI)显示出较高的值,砂质沉积物和泥质沉积物的MPI值分别在46至156和40至232之间。泥质和砂质沉积物总量态中的重金属浓度均以铁为基准进行了归一化处理。对所得数据矩阵进行了主成分分析(PCA),结果表明,泥质沉积物不稳定态的三因子模型解释率为92.22%,总量态的解释率为88.82%。主要污染源是近海油田和工业废物。这主要是由于操作设备无效且效率低下、油轮非法排放污压载水以及对违规者缺乏监督和起诉所致。

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