Lowry Michael S, Bernhard Stefan
Department of Chemistry, Princeton University, Princeton, New Jersey 08544, USA.
Chemistry. 2006 Oct 25;12(31):7970-7. doi: 10.1002/chem.200600618.
Phosphorescent iridium(III) complexes are being widely explored for their utility in diverse photophysical applications. The performance of these materials in such roles depends heavily on their excited-state properties, which can be tuned through ligand and substituent effects. This concept article focuses on methods for synthetically tailoring the properties of bis-cyclometalated iridium(III) materials, and explores the factors governing the nature of their lowest excited state.
磷光铱（III）配合物因其在各种光物理应用中的效用而受到广泛研究。这些材料在这些应用中的性能在很大程度上取决于其激发态性质，而激发态性质可通过配体和取代基效应进行调节。这篇概念文章重点介绍了合成调控双环金属化铱（III）材料性质的方法，并探讨了决定其最低激发态性质的因素。
