Schöll-Paschinger E, Dellago C
Fakultät für Physik, Universität Wien, Boltzmanngasse 5, A-1090 Wien, Austria.
J Chem Phys. 2006 Aug 7;125(5):054105. doi: 10.1063/1.2227025.
We present a derivation of the Jarzynski [Phys. Rev. Lett. 78, 2690 (1997)] identity and the Crooks [J. Stat. Phys. 90, 1481 (1998)] fluctuation theorem for systems governed by deterministic dynamics that conserves the canonical distribution such as Hamiltonian dynamics, Nose-Hoover dynamics, Nose-Hoover chains, and Gaussian isokinetic dynamics. The proof is based on a relation between the heat absorbed by the system during the nonequilibrium process and the Jacobian of the phase flow generated by the dynamics.
我们给出了Jarzynski[《物理评论快报》78, 2690 (1997)]恒等式和Crooks[《统计物理杂志》90, 1481 (1998)]涨落定理的推导,适用于由守恒正则分布的确定性动力学所支配的系统,如哈密顿动力学、诺思-胡佛动力学、诺思-胡佛链以及高斯等动力学。证明基于非平衡过程中系统吸收的热量与动力学产生的相流雅可比行列式之间的关系。