Melucci Dora, Torsi Giancarlo, Locatelli Clinio
Department of Chemistry G Ciamician, University of Bologna, Italy.
Ann Chim. 2006 Jul-Aug;96(7-8):493-504. doi: 10.1002/adic.200690050.
Analytical results are reported for the determination of inorganic species in water and sediments sampled in the Senio river ecosystem. The species determined are Cu, Pb, Cd, Zn, Co, Cr, Ni, Fe, Mn, Hg, F-, Cl-, Br, NO3-, SO4-, Na+, K+, Ca++, Mg++, NH4+ in integrated water, and Cu, Pb, Cd, Zn, Co, Cr, Ni, Fe, Mn, Hg in sediments. For all the elements, in addition to detection limits, precision and accuracy are given: the former, expressed as relative standard deviation (sr), and the latter, expressed as relative error (e), were good, being in all cases lower than 6%. Limitedly to Cu, Pb, Cd and Zn a critical comparison with voltammetric measurements is also discussed.
报告了对塞尼奥河生态系统中采集的水和沉积物中无机物种测定的分析结果。所测定的物种包括综合水样中的铜(Cu)、铅(Pb)、镉(Cd)、锌(Zn)、钴(Co)、铬(Cr)、镍(Ni)、铁(Fe)、锰(Mn)、汞(Hg)、氟离子(F-)、氯离子(Cl-)、溴离子(Br)、硝酸根离子(NO3-)、硫酸根离子(SO4-)、钠离子(Na+)、钾离子(K+)、钙离子(Ca++)、镁离子(Mg++)、铵根离子(NH4+),以及沉积物中的铜(Cu)、铅(Pb)、镉(Cd)、锌(Zn)、钴(Co)、铬(Cr)、镍(Ni)、铁(Fe)、锰(Mn)、汞(Hg)。对于所有元素,除了给出检测限外,还给出了精密度和准确度:前者以相对标准偏差(sr)表示,后者以相对误差(e)表示,结果良好,在所有情况下均低于6%。仅针对铜、铅、镉和锌,还讨论了与伏安测量的关键比较。