Guo Ming-Lin, Cao Hong-Xia
School of Materials and Chemical Engineering and Key Laboratory of Hollow Fibre Membrane Materials and Membrane Processes, Tianjin Polytechnic University, Tianjin 300160, People's Republic of China.
Acta Crystallogr C. 2006 Sep;62(Pt 9):m431-3. doi: 10.1107/S0108270106029866. Epub 2006 Aug 23.
The title complex, [Ba2Ni(C3H2O4)2(NO3)2(H2O)10]n, has a two-dimensional layer structure. The Ni atom lies on a crystallographic centre of symmetry in an octahedral NiO6 environment, and is coordinated by four malonate O atoms in a planar arrangement and by two water molecules in axial positions. The coordination of the unique Ba atom involves two nitrate O atoms, five water molecules and three malonate O atoms.
标题配合物[Ba2Ni(C3H2O4)2(NO3)2(H2O)10]n具有二维层状结构。Ni原子位于八面体NiO6环境的晶体学对称中心，由平面排列的四个丙二酸根O原子和轴向位置的两个水分子配位。独特的Ba原子的配位涉及两个硝酸根O原子、五个水分子和三个丙二酸根O原子。
