Kiran Bala, Kaushik Anubha, Kaushik C P
Department of Environmental Science and Engineering, Guru Jambheshwar University of Science & Technology, Hisar 125 001, India.
J Hazard Mater. 2007 Mar 22;141(3):662-7. doi: 10.1016/j.jhazmat.2006.07.026. Epub 2006 Jul 16.
Industrial wastewaters containing heavy metals along with high concentration of soluble salts pose a major environmental problem that needs to be remedied. The present study reports on biosorption of Cr(VI) by native isolate of Lyngbya putealis HH-15 in batch system under varying range of pH (2.0-10.0), initial metal ion concentration (10-100mg/l) and salt concentration (0-0.2%). Maximum metal removal (94.8%) took place at pH 3.0 with initial Cr concentration of 50mg/l, which got reduced (90.1%) in the presence of 0.2% salts. Adsorption equilibrium and kinetic behavior of Cr(VI) in solution was also examined. Both Langmuir and Freundlich models fitted well to explain the adsorption data (R(2)=0.90 and 0.87, respectively) at 0.2% salt concentration. Pseudo-second order kinetic model also fitted well to both the systems, viz. Cr(VI) and Cr(VI)+salt.
含有重金属以及高浓度可溶性盐的工业废水构成了一个需要补救的重大环境问题。本研究报告了在不同pH范围(2.0 - 10.0)、初始金属离子浓度(10 - 100mg/l)和盐浓度(0 - 0.2%)的分批系统中,Lyngbya putealis HH - 15的天然分离株对Cr(VI)的生物吸附情况。在pH 3.0、初始Cr浓度为50mg/l时,金属去除率最高(94.8%),在存在0.2%盐的情况下,该去除率降低至(90.1%)。还研究了溶液中Cr(VI)的吸附平衡和动力学行为。在0.2%盐浓度下,Langmuir和Freundlich模型都能很好地拟合以解释吸附数据(R²分别为0.90和0.87)。准二级动力学模型也很好地适用于这两个系统,即Cr(VI)和Cr(VI)+盐系统。