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本文引用的文献

1
mu-Oxo-bis[(2,3,12,13-tetrabromo-5,10,15, 20-tetraphenylporphyrinato)iron(III)] bis(dichloromethane) solvate.μ-氧代双[(2,3,12,13-四溴-5,10,15,20-四苯基卟啉合)铁(III)]二氯甲烷溶剂合物
Acta Crystallogr C. 2000 Oct;56 ( Pt 10):1206-7. doi: 10.1107/s0108270100010222.

双（吡啶）（2,3,12,13-四溴-5,10,15,20-四苯基卟啉）铁（II）吡啶溶剂化物

Bis (pyridine) (2,3,12,13-tetrabromo-5, 10, 15, 20-tetraphenylporphyrin) iron (II) pyridine solvate.

作者信息

Scheidt W Robert, Noll Bruce C

机构信息

University of Notre Dame, Department of Chemistry and Biochemistry, 251 Nieuwland Science Hall, Notre Dame, IN 46556-5670, USA. E-mail: w. r.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2006 Aug;62(8):m1892-m1894. doi: 10.1901/jaba.2006.62-m1892.

DOI:10.1901/jaba.2006.62-m1892
PMID:16957782
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC1560092/
Abstract

The title compound, (C(44)H(24)Br(4)N(4))(C(5)H(5)N)(2)Fe·C(5)H(5)N, is located on a two-fold axis that passes through Fe and the pyridine ligands. Only slight asymmetry, 0.010 Å elongation due to the Br substituents, is seen in the Fe-N(p) distances. The pyridine ligands are twisted 19.2° from each other.

摘要

标题化合物（C₄₄H₂₄Br₄N₄）（C₅H₅N）₂Fe·C₅H₅N位于一个通过铁和吡啶配体的二重轴上。在铁与吡啶氮（Fe-N(p)）的距离中，仅观察到由于溴取代基导致的轻微不对称，伸长了0.010 Å。吡啶配体彼此扭转了19.2°。