关于双亲性配体o-R2P(Ph)BR'2的多功能且独特的配位行为。
On the versatile and unusual coordination behavior of ambiphilic ligands o-R2P(Ph)BR'2.
作者信息
Bontemps Sébastien, Bouhadir Ghenwa, Miqueu Karinne, Bourissou Didier
机构信息
Laboratoire Hétérochimie Fondamentale et Appliquée, UMR CNRS 5069, Université Paul Sabatier, 118, route de Narbonne, F-31062 Toulouse Cedex 09, France.
出版信息
J Am Chem Soc. 2006 Sep 20;128(37):12056-7. doi: 10.1021/ja0637494.
PMID:16967941
Abstract
Monophosphine-boranes were shown to behave as bidentate ambiphilic ligands, whose structural versatility has been illustrated by the preparation of PdII and AuI complexes featuring unusual P --> M-Cl --> B and P --> M --> B interactions, respectively.
摘要
单膦硼烷表现为双齿双亲性配体，通过分别制备具有不寻常的P→M-Cl→B和P→M→B相互作用的PdII和AuI配合物，展示了其结构的多样性。
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