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对二甲苯 + 联乙酰体系(一种光学天线)的敏化磷光研究

Sensitized phosphorescence studies of p-xylene+biacetyl system, an optical antenna.

作者信息

Bayrakçeken Fuat

机构信息

Department of Electronics Engineering, Yeditepe University, Istanbul 34755, Turkey.

出版信息

Spectrochim Acta A Mol Biomol Spectrosc. 2007 Apr;66(4-5):1267-70. doi: 10.1016/j.saa.2006.06.018. Epub 2006 Jun 27.

DOI:10.1016/j.saa.2006.06.018
PMID:16968675
Abstract

p-Xylene sensitized biacetyl fluorescence and phosphorescence has been investigated and photosensitized phosphorescence lifetimes of biacetyl in the vapor phase has been determined. Attempts to detect the triplet of biacetyl by its absorption spectrum were unsuccessful, due to primarily, it is believed, to the low extinction coefficients of the triplet, and the low triplet concentrations produced by the optical pumping device at room temperature.

摘要

对对二甲苯敏化的双乙酰荧光和磷光进行了研究,并测定了双乙酰在气相中的光敏磷光寿命。试图通过其吸收光谱检测双乙酰的三重态未成功,主要原因据信是三重态的消光系数低,以及光泵浦装置在室温下产生的三重态浓度低。

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