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初始pH值对利用本地嗜酸氧化硫硫杆菌从污染土壤中生物浸出重金属的影响。

Influence of initial pH on bioleaching of heavy metals from contaminated soil employing indigenous Acidithiobacillus thiooxidans.

作者信息

Kumar R Naresh, Nagendran R

机构信息

Centre for Environmental Studies, Anna University, Chennai 600 025, India.

出版信息

Chemosphere. 2007 Jan;66(9):1775-81. doi: 10.1016/j.chemosphere.2006.07.091. Epub 2006 Sep 18.

Abstract

Bioleaching of heavy metals from contaminated soil was carried out employing indigenous sulfur oxidizing bacterium Acidithiobacillus thiooxidans. Experiments were carried out to assess the influence of initial pH of the system on bioleaching of chromium, zinc, copper, lead and cadmium from metal contaminated soil. pH at the end of four weeks of bioleaching at different initial pH of 3-7 was between 0.9 and 1.3, ORP between 567 and 617mV and sulfate production was in the range of 6090-8418mgl(-1). Chromium, zinc, copper, lead and cadmium solubilization ranged from "59% to 98%" at different initial pH. A. thiooxidans was not affected by the increasing pH of the bioleaching system towards neutral and it was able to utilize elemental sulfur. The results of the present study are encouraging to develop the bioleaching process for decontamination of heavy metal contaminated soil.

摘要

利用本地硫氧化细菌嗜酸氧化硫硫杆菌对污染土壤中的重金属进行生物浸出。进行了实验,以评估系统初始pH值对从金属污染土壤中生物浸出铬、锌、铜、铅和镉的影响。在3 - 7的不同初始pH值下进行四周生物浸出后,pH值在0.9至1.3之间,氧化还原电位在567至617mV之间,硫酸盐产量在6090 - 8418mg l(-1)范围内。在不同初始pH值下,铬、锌、铜、铅和镉的溶解率在“59%至98%”之间。嗜酸氧化硫硫杆菌不受生物浸出系统pH值向中性增加的影响,并且能够利用元素硫。本研究结果对于开发用于重金属污染土壤去污的生物浸出工艺具有鼓舞作用。

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