Kuninobu Yoichiro, Nishina Yuta, Nakagawa Chie, Takai Kazuhiko
Division of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University, Tsushima, Okayama 700-8530, Japan.
J Am Chem Soc. 2006 Sep 27;128(38):12376-7. doi: 10.1021/ja065643e.
A rhenium complex, [ReBr(CO)3(thf)]2, catalyzed reactions of aromatic ketimines with aldehydes to give isobenzofuran derivatives in good to excellent yields. In contrast to ruthenium and rhodium catalysts, aldehydes, which are polar unsaturated molecules, inserted into the C-H bond after activation by the rhenium complex.
一种铼配合物[ReBr(CO)₃(thf)]₂催化芳族酮亚胺与醛的反应，以良好至优异的产率生成异苯并呋喃衍生物。与钌和铑催化剂不同，醛作为极性不饱和分子，在被铼配合物活化后插入到C-H键中。
