Muniappan Sankar, Lipstman Sophia, Goldberg Israel
School of Chemistry, Sackler Faculty of Exact Sciences, Tel-Aviv University, Ramat-Aviv, 69978 Tel-Aviv, Israel.
Acta Crystallogr C. 2006 Oct;62(Pt 10):m495-7. doi: 10.1107/S0108270106035840. Epub 2006 Sep 21.
The crystal structure of the title compound, {[Zn(C52H36N4O8)].2C4H9NO}n, consists of two-dimensional coordination polymers of the six-coordinate zinc-porphyrin unit [Zn-N = 2.039 (2) and 2.061 (2) A, and Zn-O = 2.540 (2) A], which intercalate between the molecules of N,N-dimethylacetamide solvent. The Zn atom lies on an inversion centre.
标题化合物{[Zn(C₅₂H₃₆N₄O₈)].2C₄H₉NO}ₙ的晶体结构由六配位锌卟啉单元的二维配位聚合物组成[Zn-N = 2.039 (2) Å和2.061 (2) Å,Zn-O = 2.540 (2) Å],这些聚合物插层在N,N-二甲基乙酰胺溶剂分子之间。锌原子位于一个对称中心上。