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Nickel catalyzed stereoselective conjugate addition of dimethylzinc upon aldimines across 1,3-dien-8-ynes and 1,3-dien-9-ynes.

作者信息

Kimura Masanari, Mori Masahiko, Mukai Nahoko, Kojima Keisuke, Tamaru Yoshinao

机构信息

Department of Applied Chemistry, Faculty of Engineering, Nagasaki University, 1-14 Bunkyo-Machi, Nagasaki, 852-8521, Japan.

出版信息

Chem Commun (Camb). 2006 Jul 14(26):2813-5. doi: 10.1039/b605728d.

DOI:10.1039/b605728d
PMID:17009472
Abstract

Ni(acac)2 catalyzes the five-component connection reaction of Me2Zn, alkynes, diene (of 1,3-dien-8-ynes and 1,3-dien-9-ynes), aldehydes and anisidine to furnish cyclic dienyl amines anti-2 with high remote 1,5-diastereoselectivity.

摘要

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