Yeori Adi, Goldberg Israel, Shuster Michael, Kol Moshe
School of Chemistry, Raymond and Beverly Sackler Faculty of Exact Sciences, Tel Aviv University, Ramat Aviv, Tel Aviv 69978, Israel.
J Am Chem Soc. 2006 Oct 11;128(40):13062-3. doi: 10.1021/ja0647654.
Chiral Salan ligands were found to wrap in a highly diastereoselective manner around zirconium leading to C2-symmetric complexes of predetermined chirality at the metal. These complexes led to active polymerization of higher olefins, their activity and isospecific induction depending on the nature of the phenolate substituents.
人们发现手性Salan配体以高度非对映选择性的方式环绕在锆周围，形成金属上具有预定手性的C2对称配合物。这些配合物可引发高级烯烃的活性聚合反应，其活性和等规诱导作用取决于酚盐取代基的性质。
