Ishida Yasuhiro, Amano Sayaka, Iwahashi Nobutaka, Saigo Kazuhiko
Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, Hongo, Tokyo 113-8658, Japan.
J Am Chem Soc. 2006 Oct 11;128(40):13068-9. doi: 10.1021/ja064969k.
A cross-linked polymer, prepared by the in situ polymerization of a thermotropic columnar liquid crystal, was found to work as a host with a flexible framework, which was reminiscent of intercalation hosts, such as clays, graphites, and coordination polymers. The structural order of the cross-linked polymer was reversibly switched by changing the amount or shape of a guest incorporated in the polymer.
通过热致柱状液晶的原位聚合制备的交联聚合物被发现可作为具有柔性骨架的主体，这让人联想到诸如粘土、石墨和配位聚合物等插层主体。通过改变掺入聚合物中的客体的量或形状，交联聚合物的结构有序性可被可逆地切换。
